The programs to put on depend on what you like to do and its intended use. I don't know if Toshiba ever made desktops, so i'll assume you've got a laptop. For starters, you'll need some sort of word proccessor. Even though you think you don't need one, one day you'll be on a plane(or whatever) and say to yourself "crap, I knew I should have typed that report earlier!" and you'll need more that the text thing Windows 3.11 has. And if you dont install one, the same day you say the thing about the report, you'll say "crap! I knew I should have listened to Ryan!."
Then, you'll need entertainment, more than what Windows has to offer. I've got Doom I, II, the Duke Nukem series, and Quake I. But thats what I am interested in. Maybe you like text-based adventure games. Either way, install a few games, so you have choices of entertainment, and so when you beat one(again) when your away from home, you can turn to another. I also recomend downloading CD drivers from Toshiba, so you can listen to music and read stuff on CD.
Those are just the basics. Possibilities with Toshiba are endless, though. Maybe you'll want Flight Simulator, perhaps a home builder, or some informational disks. Oh, and as a last note, I have an intresting suggestion. What I did, is I copied all my Windows 3.11 disks to my newer computer HD, and all the drivers and stuff(execpet big games) I installed ontop my laptop. Then I burned it to a "recovery disc." SO if my laptop ever dies(I tend to kill old O/S, on accident) you don't have to download all those drivers and put 'em on floppy again. Just install DOS, put the CD driver on floppy disk, and copy the drivers back to the Toshiba for installation. You'll have to copy them though, as Toshiba likes to pack the drivers into self-inflating files, and you can't inflate files onto a CD with such an old PC.
Dang that was longer than intended!
--Ryan