It's interesting that the labels say "PCSIG disk", since PC-SIG published (IBM) PC software.
According to this catalog, PCSIG disks #1022 and #1023 should contain Qmodem SST v4.1. FWIW, the wording on the labels makes me think that "MSDOS" refers to the disk format, not the contents.
[EDIT] Contents of the above-mentioned PCSIG disks: 1022, 1023