Old thread, but:
9V AC is connected to the user port. It might be used by some RS232 level converters, maybe some EPROM programmers and such. Check each user port accessory.
Otherwise the unregulated DC is used for the cassette motor, and obviously the 5V regulator.
There is an old thread at IIRC the denial/sleepingelephant forum with the conclusion that a VIC 20 with built in rectifier+regulator can run at 10-12V DC and at 10V it actually runs a bit cooler than with the regular 9V AC.
As for finding a transformer, I recommend going through the bins at thrift stores / flea markets. Just feel the weight of the mains adapters / wall warts. Anyone that is light weight isn't even worth reading the label on as it will be a switched supply that outputs DC (or worst case high frequency AC which I think is a thing for LED drivers).
If they charge like €1 or so for each adapter, I would kind of grab all of the ones that supplies various somewhat reasonable AC voltages as they might come in handy and will over time be rarer and rarer to find for cheap.
Otherwise, it's just a transformer. You can buy the transformer itself from most electronic components suppliers, and since it's not a super cheap thing also check surplus sellers, eBay and such. Then just put the transformer, a suitable fuse, mains intake connector or mains cord strain relief and maybe a mains power switch in any suitable box. Maybe add a LED with a series resistor (and possibly a small bridge rectifier) to indicate that output power is on.
For the European two prong VIC 20's, you can surprisingly use RCA female wire connectors! They fit on the prongs of the chassis intake connector on the VIC 20. I would recommend using two red connectors and put a warning label clearly stating that it's 9V AC for powering a VIC 20. That way you don't need to 3D print a connector or replace the intake connector (or back feed through the 9V AC pins on the user port).
Afaik the US VIC 20 used the same connector as some electric razors used for 110-120V AC mains. Sorry for being a tiny bit political but that being legal has a strong third world vibe. Like with a mains cord for a razor and the VIC 20 in the off position nothing would break but there would be a 50% risk that the signal ground of the VIC 20 would be connected to live mains power.
Either way, you should be able to find suitable electric razor power cords. IIRC these might have special wires with more strands than regular wires, but each strand being thinner, to allow for flexing a lot more as you'd move the cord each time you use your shaver. Don't know if that makes it more challenging to connect to or not though?