Just what the documentation says, +5, -5, +12, -12. That -5 is very important to the old 16-64K mobo memory--and not all third-party PSUs supply it.
You can measure the voltages directly on the expansion card ege connectors, all referenced to position B1:
B3 = +5
B5 = -5
B7 = -12
B9 = +12
On the disk drives, Black = gnd, Yellow = +12, Red = +5. No negative voltages there.