Of the large size floppies, (not dimensional but storage space), I remember the LS120. I bought one of those crappy drives at Best Buy at a premium price back in the 90's, and the 120 meg floppies were expensive as well. (I think around $10. each, as I recall and the drive was like $190. or so. Yikes! But it seemed to be the way to go, at the time. I needed more and more storage space. Well, the LS120, at least in my situation, was more than slow - it dragged on and on. It took forever to get even a directory off the floppy. I learned to really dislike the thing. But I got myself locked into the system by purchasing so many disks that I couldn't get out. I had too much invested in the blasted things.
Anyway, here's an old Cyrix powered 133 Mhz machine with my LS120 (it's the whiter looking drive toward the center). It appears just like a standard 1.44 M floppy, and it will even work as a standard 1.44 M floppy drive, but it's specialty was the 120 M floppies.
http://www.vintage-computer.com/vcforum/picture.php?albumid=14&pictureid=287
Here's a 120 meg floppy for it. I saved about a half dozen of these things for posterity. They work also as a 1.44 meg floppy. A tad wasteful, - kind of like having a silver plated floppy
http://www.vintage-computer.com/vcforum/picture.php?albumid=14&pictureid=288